Reduction of sludge formed during a coagulation treatment of Ridomil Gold by means of non-thermal quenched plasma pre-treatment

Chemical coagulation and adsorption, despite many drawbacks, are actually the main techniques used for the removal of pollutants from aqueous solution; however, these techniques are becoming ineffective due to the exponential increase in the amount and complexity of discharged pollutants; thus, the sludge treatment process became a more complex challenge. The present study focuses on the way to reduce the quantity of sludge formed during the removal of Ridomil Gold, a widely used pesticide-fungicide in agriculture. Results revealed that pre-treatment of initial waste solution by the gliding arc (Glidarc), a source of non-thermal plasma, leads to a significant reduction of the sludge formed during the coagulation treatment. For a 20-min pre-treated effluent Glidarc followed by chemical coagulation, there was a reduction in the volume of sludge formed in the order of 90 and 80% for alum and ferric sulfate coagulants respectively without reducing the performance of pesticide removal. Therefore, there is a positive synergism between treatment by chemical coagulation and plasma treatment. These results suggest that the Glidarc can be an effective solution for the reduction of sludge obtained during treatment by coagulation.     

Monitoring saltwater intrusion in Rupert Bay,Québec,Canada, after the partial diversion of a major tributary

As part of a large hydroelectric project in northern Québec (Canada), a portion of the flow of the Rupert River was diverted toward the existing La Grande hydroelectric complex. As a result of the partial diversion, the discharge of the Rupert River at its mouth is reduced by an average of 50% annually. This corresponds to an 18% decrease in the total freshwater inflow into the bay and, thus, to a shift of the upstream limit of the saltwater intrusion in Rupert Bay. Changes in saltwater intrusion had been predicted numerically as part of the project’s environmental impact assessment (EIA). In the project’s conditions of authorization, monitoring the hydraulic conditions and the extent of saltwater intrusion in the Rupert Bay was required by government authorities. The objective of this paper is to present the results of this environmental monitoring and, more specifically, to validate the modifications predicted in the EIA in terms of both saltwater intrusion limit and hydraulic conditions in the Rupert Bay. Results obtained during 2 years of monitoring are within the predicted trends and order of magnitude of changes anticipated in the EIA. The results, thus, confirm that the shift of the upstream limit of the saltwater front along the channels of the bay was conservatively predicted by numerical modeling.     

Spatial distribution characteristics of soil organic carbon in subtropical forests of mountain Lushan,China

The study on the spatial distribution of forest soil organic carbon (SOC) is of great significance for accurate assessment of carbon storage in forest ecosystems. In the present study, by taking eight kinds of forest soils of Mountain Lushan in the subtropical area as the research object, we studied the spatial distribution characteristics of SOC in this mountainous area. The results showed that the SOC content and SOC density (SOCD) of main forest types in the Mountain Lushan were lower than the national and the world average. The soil layer of Lushan forest was thinner, and the SOC and active SOC (ASOC) contents of different forest types and SOCDs are the highest in the surface soil. SOCD of the topsoil accounts for 32.64–54.03% of the total SOCD in the whole soil profile. Surface litter is an important source of SOC, and the different vegetation types are the important reason for the different spatial distribution of SOC in this area. Soil SOC contents in the high-altitude forest (bamboo forest, deciduous broadleaf forest, Pinus taiwanensis forest, evergreen-deciduous forest, and coniferous-broadleaved mixed forest) were higher than those in the low-altitude forest (evergreen broadleaf forest, shrub, and Pinus massoniana forest). However, the difference in SOC content exhibited at the altitude gradient is significantly lower than that in SOC in the soil profile. This indicates that both soil depth and elevation are the important factors that affected SOC distribution. However, the influence of soil depth on spatial distribution of SOC may be more complex than that of altitude. Vegetation types and soil properties are the main reasons for the large differences of reduction rate in the contents of SOC and ASOC.     

Plant Species Richness and Developmental Morphology Stage Influence Mycorrhizal Patagonia Plants Root Colonization

The objectives of this study were to determine the percentage of root colonization by arbuscular mycorrhizal (AM) fungi at various levels of plant species richness and developmental morphology stages in various perennial grass, and herbaceous and woody dicots species using experimental plots during 2013 and 2014. An auger was used to obtain six replicate root + soil samples at each sampling time on each of the study parameters. Roots were washed free of soil, and percentage AM was determined. The shrub Larrea divaricata was the species which showed the lowest percentage of colonization by AM at the vegetative developmental morphology stage at the monocultures and six-species-mixtures on the experimental plots. Dicots, but not grass, species showed a greater percentage colonization by AM fungi at the greatest (i.e., six-species-mixtures) than lowest (i.e., monocultures) species richness. Although at different degrees of species richness and developmental morphology stages, the perennial grasses Nassella longiglumis and N. tenuis, the herbaceous dicot Atriplex semibaccata, and the shrubs L. divaricata and Schinus fasciculatus showed a greater (p < 0.050) percentage colonization by AM fungi during the second than the first study year. Even though it was species- and sampling time-dependent, percentage colonization by AM fungi increased as species richness also increased most of the times. Our results demonstrated that the plant species differences in percentage colonization by AM fungi in the experimental plots were species richness-, developmental morphology stage-, and sampling-time dependents.     

Discrete-choice experiments valuing local environmental impacts of renewables: two approaches to a case study in Portugal

Despite the often mentioned environmental benefits associated with transition from fossil fuels to renewable energy sources, their use for electricity production has non-negligible negative environmental impacts. The most commonly mentioned in surveys concern different types of landscape impacts, impacts on the fauna and flora, and noise. These impacts differ by size and location of plants, and by source of energy, rendering the policy decision complex. In addition, there are other welfare issues to take into consideration, as positive and negative environmental impacts are not evenly distributed among population groups. This paper proposes to compare the welfare impacts of renewable energy sources controlling for the type of renewable as well as the specific environmental impact by source. To this end, two discrete-choice experiments are designed and applied to a national sample of the Portuguese population. In one case, only individual negative impacts of renewables are used, and in another case, the negative impacts interact with a specific source. Results show the robustness of discrete-choice experiments as a method to estimate the welfare change induced by the impacts of renewable energy sources. Overall, respondents are willing to pay to reduce the environmental impacts, thus making compensation for local impacts feasible. Moreover, the estimations reveal that respondents are significantly sensitive to the detrimental environmental effects of specific renewable energy sources, being willing to pay more to use these sources of energy relative to others.     

Physical separation,mechanical enrichment and recycling-oriented characterization of spent NiMH batteries

Nickel–metal hydride (NiMH) batteries contain high amount of industrial metals, especially iron, nickel, cobalt and rare earth elements. Although the battery waste is a considerable secondary source for metal and chemical industries, a recycling process requires a suitable pretreatment method before proceeding with recovery step to reclaim all valuable elements. In this study, AA- and AAA-type spent NiMH batteries were ground and then sieved for size measurement and classification. Chemical composition of the ground battery black mass and sorted six different size fractions were determined by an analytical technique. Crystal structures of the samples were analyzed by X-ray diffraction. Results show that after mechanical treatment, almost 87 wt% of the spent NiMH batteries are suitable for further recycling steps. Size classification by sieving enriched the iron content of the samples in the coarse fraction which is bigger than 0.25 mm. On the other hand, the amounts of nickel and rare earth elements increased by decreasing sample size, and concentrated in the finer fractions. Anode and cathode active materials that are hydrogen storage alloy and nickel hydroxide were mainly collected in finer size fraction of the battery black mass.     

Improvement of Impact Toughness of Biodegradable Poly(butylene succinate) by Melt Blending with Sustainable Biobased Glycerol Elastomers

Poly(butylene succinate) (PBS) was melt blended with glycerol based polyesters (PGS) synthesized from pure and technical glycerol aiming to improve the impact strength of PBS. It was found that after addition of 30 wt% PGS to PBS its impact strength was significantly increased by 344% (from 31.9 to 110 J/m) and its elongation at break was maintained at 220%. Infrared spectra of the blends showed the presence of hydroxyl groups from the PGS phase suggesting that hydrogen bonding between the phases could be responsible for a good stress transfer and an efficient toughening in the PBS/PGS blends. Scanning electron microscopy imaging showed a good dispersion of PGS phase into PBS with a PGS particle size of 10 μm and less and no agglomeration. Addition of PGS to PBS was shown to be an effective strategy for improvement of PBS impact resistance without serious detrimental effects on its thermal and rheological properties.     

Sb release characteristics of the solid waste produced in antimony mining smelting process

Sb release characteristics of blast furnace slag, mining waste rock and tailing sand were investigated in static immersion and dynamic leaching test. These three kinds of waste samples were collected from the antimony mine in Lengshuijiang, China, produced in mining smelting process. Effects of solid/liquid ratio, sample size and pH of leaching solution on Sb release characteristics were inspected based on the analysis of scanning electron microscope, pH and EC of leachate. The optimal parameters for Sb leaching of each sample were analyzed. For blast furnace slag and mining waste rock, Sb release contents increased along with the decline of solid/liquid ratio. The maximum accumulative release contents were 42.13, 34.26 mg/kg at the solid/liquid ratio of 1:20. While Sb release content for tailing sand decreased first and then increased with the reduction of solid/liquid ratio. When the solid/liquid ratio was 1:5, the accumulative Sb release content reached the most (24.30 mg/kg). Sb release content of mining waste rock increased with the drop of leaching solution pH, with the highest accumulative release content of 26.01 mg/kg at pH 2.0. Sb release contents of blast furnace slag and tailing sand showed positive correlation with the variation of leaching solution pH. The maximum accumulative release contents of these two samples were 215.91 and 147.83 mg/kg, respectively, when leaching solution pH was 7.0. In summary, Sb release capacity of the three samples in descending order was tailing sand, blast furnace slag and mining waste rock. pH and EC of the leachate in dynamic test varied independently with the initial pH of leaching solution while showing close relationship with mineral hydrolysis in the waste.     

Production of Curdlan Grown on Cassava Starch Waste Hydrolysates

Cassava starch waste hydrolysates (CSWHs) with different degrees of polymerisation, i.e., CSWHs-1, CSWHs-2 and CSWHs-3, were prepared through the hydrolysis of cassava starch waste with thermostable a-amylase from Thermococcus sp. HJ21. The prepared CSWHs were then used as a carbon source for curdlan production with Alcaligenes faecalis ATCC 31749. The amount of curdlan produced and the glucosyltransferase activity during curdlan synthesis increased more obviously when CSWHs-2 was used as the carbon source than when glucose was used. Using both carbon sources, the maximum curdlan production was observed at day 5, and the maximum glucosyltransferase activity was observed at day 4. Glucosyltransferase activity decreased thereafter, and biomass continued to increase until the end of the experiment (day 6). Results indicated that the enhanced curdlan production with CSWHs as the carbon source was highly correlated with glucosyltransferase activity.     

Violence in environmental conflicts: the need for a multidimensional approach

Although studies on environmental conflicts have engaged with the subject of violence, a multidimensional approach has been lacking. Using data from 95 environmental conflicts in Central America, we show how different forms of violence appear and overlap. We focus on direct, structural, cultural, slow, and ecological forms of violence. Results suggest that the common understanding of violence in environmental conflicts as a direct event in time and space is only the tip of the iceberg and that violence can reach not only environmental defenders, but also communities, nature, and the sustainability of their relations.